Saturday 17 May 2008 7:00pm - 8:00pm

The King and Queen of daytime TV Phillip Schofield and Fern Britton will be finding out whether some of the nation’s favourite celebrity couples really were made for one another.

In the sixth episode of the eight part series, celebrities willing to put their relationships on the line include Atomic Kitten singer Natasha Hamilton and her new husband Riad Eraji, TV star David Dickinson and his wife Lorne, plus actor Anthony Head and his wife Sarah. They will all compete for big cash prizes for a charity of their choice.

David and Lorne have been together for 39 years, the longest relationship of the series, whilst Riad and Natasha have been married for just three months.

Riad explains how he proposed and reveals Natasha’s bad habits in bed, while she airs her frustration as he leaves chewing gum all over their new home. They have even been revising for the show whilst on holiday before filming.

Lorne Dickinson reveals that her husband talks far too much but he criticises her for repeating herself.

The show, originally hosted by Derek Batey, will not only see hosts Phillip Schofield and Fern Britton question the celebrities about their relationships, but will also get an insight into their home life as All Star Mr & Mrs takes a trip around each of the couples homes.

As each pair plays, one half will be sent off to the sound proofed booth whilst their other half will be quizzed on their life together. The other half of the couple will then return and be challenged to match their partner’s answers in a bid to win points.

After two rounds the couple with the most points will go on to play for big cash prize of £30,000 for a charity of their choice plus there will be a few more surprises along the way.

All Star Mr & Mrs is a Celador production for ITV1.